Windows 10 gives you the option to open new explorer windows to “This PC” instead of the quick access layout and also gives you the option to disable showing recently used files in Quick access and showing frequently used folders in Quick access, however their is no GPO to easily configure any of these settings.
It’s easy to customise Windows explorer to your linking on a single PC, however if you want to make these changes for multiple users using multiple computers on a domain you really need to be making the change though group policy.
